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JEE Advanced 2021 · Thermal Properties of Matter

A small object is placed at the center of a large evacuated hollow spherical container. Assume that the container is maintained at 0 K. At time t=0,t = 0, the temperature of the object is 200 K. The temperature of the object becomes 100 K at t=t1t = t_{1} and 50 K at t=t2.t = t_{2}. Assume the object and the container to be ideal black bodies. The heat capacity of the object does not depend on temperature. The ratio (t2/t1)(t_{2}/t_{1}) is ___________.

Answer: 99

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Written solution

Step 1: Express the net rate of heat loss.

By the Stefan-Boltzmann law, the net power radiated by the black body to the container at 0 K0\,\text{K} is:

Pnet=σAT4P_{\text{net}} = \sigma A T^4

Step 2: Formulate the differential equation.

The rate of change of the object's thermal energy is related to its heat capacity CC and temperature TT:

CdTdt=−σAT4C \frac{dT}{dt} = -\sigma A T^4

Step 3: Separate variables and integrate.

Rearrange the terms to separate the variables TT and tt:

dTT4=−σACdt\frac{dT}{T^4} = -\frac{\sigma A}{C} dt

Integrate both sides from the initial state at t=0t = 0 where T=T0T = T_0:

∫T0TdTT4=−σAC∫0tdt\int_{T_0}^{T} \frac{dT}{T^4} = -\frac{\sigma A}{C} \int_{0}^{t} dt −13(1T3−1T03)=−σACt-\frac{1}{3}\left(\frac{1}{T^3} - \frac{1}{T_0^3}\right) = -\frac{\sigma A}{C} t

Step 4: Solve for time tt.

Express the time tt as a function of temperature TT:

t=C3σA(1T3−1T03)t = \frac{C}{3\sigma A} \left(\frac{1}{T^3} - \frac{1}{T_0^3}\right)

Step 5: Write expressions for t1t_1 and t2t_2.

Substitute the given temperatures T0=200 KT_0 = 200\,\text{K}, T=100 KT = 100\,\text{K} for t1t_1, and T=50 KT = 50\,\text{K} for t2t_2:

t1=C3σA(11003−12003)t_1 = \frac{C}{3\sigma A} \left(\frac{1}{100^3} - \frac{1}{200^3}\right) t2=C3σA(1503−12003)t_2 = \frac{C}{3\sigma A} \left(\frac{1}{50^3} - \frac{1}{200^3}\right)

Step 6: Calculate the ratio of the times.

Divide t2t_2 by t1t_1 to find the ratio:

t2t1=1503−1200311003−12003\frac{t_2}{t_1} = \frac{\dfrac{1}{50^3} - \dfrac{1}{200^3}}{\dfrac{1}{100^3} - \dfrac{1}{200^3}}

Multiply the numerator and denominator by 2003200^3:

t2t1=(20050)3−1(200100)3−1\frac{t_2}{t_1} = \frac{\left(\dfrac{200}{50}\right)^3 - 1}{\left(\dfrac{200}{100}\right)^3 - 1} t2t1=43−123−1\frac{t_2}{t_1} = \frac{4^3 - 1}{2^3 - 1} t2t1=637\frac{t_2}{t_1} = \frac{63}{7} t2t1=9\frac{t_2}{t_1} = 9

Answer: 99

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