arthham

JEE Advanced 2026 · Thermal Properties of Matter

As shown in the figure, an insulated container is fitted with a thermally conducting but immovable partition (P1P_1) and a freely movable but thermally insulated piston (P2P_2). The partition P1P_1 with thermal conductivity KK, cross sectional area AA and width xx divides the container into two sections, S1S_1 and S2S_2, each containing one mole of a monoatomic gas. The piston P2P_2 moves freely such that the gas in S2S_2 is always at the atmospheric pressure. Initially, the difference between the temperatures of S1S_1 and S2S_2 is ΔT0\Delta T_0. The time it takes for the temperature difference to become ΔT02\frac{\Delta T_0}{2} is nxR/KAnxR/KA, where RR is the universal gas constant. The value of nn is: [Given: ln⁡2≈0.7\ln 2 \approx 0.7]

Answer: 0.660.66

Watch this solved on the board The full walkthrough, written out a line at a time with narration explaining each step as it appears. Pause anywhere and ask why a line is there. Free to watch

Or read the worked solution below. Jump to the steps ↓

Written solution

Step 1: Identify the thermodynamic processes for each section.

Section S1S_1 has a constant volume, while section S2S_2 remains at constant atmospheric pressure.

CV=32RC_{V} = \frac{3}{2}R CP=52RC_{P} = \frac{5}{2}R

Step 2: Express the rate of heat transfer through the partition.

The heat flow rate from S1S_1 to S2S_2 depends on the temperature difference ΔT=T1−T2\Delta T = T_1 - T_2.

dqdt=KAx(T1−T2)\frac{dq}{dt} = \frac{KA}{x}(T_1 - T_2) dqdt=KAxΔT\frac{dq}{dt} = \frac{KA}{x}\Delta T

Step 3: Relate the heat transfer to the temperature changes.

For section S1S_1, the heat lost reduces its internal energy at constant volume.

dT1dt=−23Rdqdt\frac{dT_1}{dt} = -\frac{2}{3R}\frac{dq}{dt}

For section S2S_2, the heat gained increases its enthalpy at constant pressure.

dT2dt=25Rdqdt\frac{dT_2}{dt} = \frac{2}{5R}\frac{dq}{dt}

Step 4: Set up the differential equation for the temperature difference.

Subtract the temperature change rates to find the rate of change of ΔT\Delta T.

d(ΔT)dt=dT1dt−dT2dt\frac{d(\Delta T)}{dt} = \frac{dT_1}{dt} - \frac{dT_2}{dt} d(ΔT)dt=−(23R+25R)dqdt\frac{d(\Delta T)}{dt} = -\left(\frac{2}{3R} + \frac{2}{5R}\right)\frac{dq}{dt} d(ΔT)dt=−1615R(KAxΔT)\frac{d(\Delta T)}{dt} = -\frac{16}{15R}\left(\frac{KA}{x}\Delta T\right) d(ΔT)dt=−16KA15xRΔT\frac{d(\Delta T)}{dt} = -\frac{16KA}{15xR}\Delta T

Step 5: Solve the differential equation for the time elapsed.

Integrate the equation from the initial state to the state where the temperature difference is halved.

∫ΔT0ΔT02d(ΔT)ΔT=−16KA15xR∫0tdt\int_{\Delta T_0}^{\frac{\Delta T_0}{2}} \frac{d(\Delta T)}{\Delta T} = -\frac{16KA}{15xR}\int_0^t dt ln⁡(12)=−16KA15xRt\ln\left(\frac{1}{2}\right) = -\frac{16KA}{15xR}t t=1516ln⁡2xRKAt = \frac{15}{16}\ln 2 \frac{xR}{KA}

Step 6: Calculate the value of nn.

Compare the expression for tt to the given form t=nxRKAt = \frac{nxR}{KA}.

n=1516ln⁡2n = \frac{15}{16}\ln 2 n≈1516×0.7n \approx \frac{15}{16} \times 0.7 n≈0.66n \approx 0.66

Answer:

The value of nn is approximately 0.660.66 (or 1516ln⁡2\frac{15}{16}\ln 2).

More from Thermal Properties of Matter

All 20 Thermal Properties of Matter questions →