As shown in the figure, an insulated container is fitted with a thermally conducting but immovable partition () and a freely movable but thermally insulated piston (). The partition with thermal conductivity , cross sectional area and width divides the container into two sections, and , each containing one mole of a monoatomic gas. The piston moves freely such that the gas in is always at the atmospheric pressure. Initially, the difference between the temperatures of and is . The time it takes for the temperature difference to become is , where is the universal gas constant. The value of is: [Given: ]
Answer:
Or read the worked solution below. Jump to the steps ↓
Written solution
Step 1: Identify the thermodynamic processes for each section.
Section has a constant volume, while section remains at constant atmospheric pressure.
Step 2: Express the rate of heat transfer through the partition.
The heat flow rate from to depends on the temperature difference .
Step 3: Relate the heat transfer to the temperature changes.
For section , the heat lost reduces its internal energy at constant volume.
For section , the heat gained increases its enthalpy at constant pressure.
Step 4: Set up the differential equation for the temperature difference.
Subtract the temperature change rates to find the rate of change of .
Step 5: Solve the differential equation for the time elapsed.
Integrate the equation from the initial state to the state where the temperature difference is halved.
Step 6: Calculate the value of .
Compare the expression for to the given form .
Answer:
The value of is approximately (or ).