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JEE Advanced 2024 · Thermal Properties of Matter

The specific heat capacity of a substance is temperature dependent and is given by the formula C=C = kT, where k is a constant of suitable dimensions in SI units, and T is the absolute temperature. If the heat required to raise the temperature of 1 kg of the substance from -73°C to 27°C is nk, the value of n is ____. [Given:0K=−273°C.]: 0 K = -273°C.]

Answer: 2500025000

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Written solution

Step 1: Identify the given parameters and convert temperatures to Kelvin.

Convert the temperatures from Celsius to Kelvin using the relation T(K)=T(∘C)+273T(\text{K}) = T(^\circ\text{C}) + 273.

m=1 kgm = 1\ \text{kg} T1=−73∘C=200 KT_1 = -73^\circ\text{C} = 200\ \text{K} T2=27∘C=300 KT_2 = 27^\circ\text{C} = 300\ \text{K} C=kTC = kT Q=nkQ = nk

Step 2: Set up the differential equation for heat.

Since the specific heat capacity is temperature-dependent, express the heat required for an infinitesimal temperature change dTdT.

dQ=mCdTdQ = m C dT dQ=mkTdTdQ = m k T dT

Step 3: Integrate to find the total heat.

Integrate the expression from the initial temperature T1T_1 to the final temperature T2T_2.

Q=∫T1T2mkT dTQ = \int_{T_1}^{T_2} m k T \, dT Q=mk[T22]T1T2Q = mk \left[ \frac{T^2}{2} \right]_{T_1}^{T_2} Q=mk2(T22−T12)Q = \frac{mk}{2} \left( T_2^2 - T_1^2 \right)

Step 4: Substitute the values into the integrated equation.

Substitute the given values of mass and temperatures.

Q=1⋅k2(3002−2002)Q = \frac{1 \cdot k}{2} \left( 300^2 - 200^2 \right) Q=k2(90000−40000)Q = \frac{k}{2} (90000 - 40000) Q=25000kQ = 25000k

Step 5: Compare with the given heat expression to find nn.

Equate the calculated heat to the given expression Q=nkQ = nk.

nk=25000knk = 25000k n=25000n = 25000

Answer: 25000

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