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JEE Advanced 2026 · Thermodynamics

A quasi-static cycle of a monoatomic ideal gas contains an isothermal process (ab), followed by an isochoric process (bc) and an adiabatic process (ca) as shown in the figure. The volumes of the gas are V1V_1 and V2V_2 at aa and bb, respectively. If the cycle has heat input QinQ_{\text{in}} and output QoutQ_{\text{out}}, then the efficiency of the cycle is defined as η=Qin−QoutQin\eta = \frac{Q_{\text{in}} - Q_{\text{out}}}{Q_{\text{in}}}. The correct statement(s) is/are: [Given: ln⁡2≈0.7\ln 2 \approx 0.7]

Answers: A. If V2/V1=8V_2/V_1 = 8, the heat released in the process bc is smaller than the heat absorbed in the process ab. · B. For a given value of V2/V1V_2/V_1, η\eta does not depend on the temperature of the isothermal process. · C. If V2/V1=8V_2/V_1 = 8, then the temperature of the gas at a is 4 times the temperature of the gas at c.

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Written solution

Step 1: Identify the properties of the gas and the processes.

For a monoatomic ideal gas, the ratio of specific heats γ\gamma and the molar heat capacity at constant volume CvC_v are:

γ=53\gamma = \frac{5}{3} Cv=32RC_v = \frac{3}{2}R

The processes in the cycle are:

  • a→ba \to b: Isothermal expansion at temperature TT from volume V1V_1 to V2V_2.
  • b→cb \to c: Isochoric cooling at volume V2V_2 from temperature TT to TcT_c.
  • c→ac \to a: Adiabatic compression from volume V2V_2 to V1V_1.

Step 2: Analyze the heat exchange in each process.

For the isothermal process a→ba \to b, the heat absorbed is:

Qab=nRTln⁡(V2V1)Q_{ab} = nRT\ln\left(\frac{V_2}{V_1}\right)

Since V2>V1V_2 > V_1, Qab>0Q_{ab} > 0, which represents the heat input QinQ_{\text{in}}.

For the isochoric process b→cb \to c, the heat released is:

Qbc=nCv(T−Tc)Q_{bc} = nC_v(T - T_c)

This represents the heat output QoutQ_{\text{out}}.

For the adiabatic process c→ac \to a:

Qca=0Q_{ca} = 0

Step 3: Relate the temperatures using the adiabatic process.

For the adiabatic process c→ac \to a:

TcV2γ−1=TV1γ−1T_c V_2^{\gamma-1} = T V_1^{\gamma-1}

Substitute γ=53\gamma = \frac{5}{3}:

Tc=T(V1V2)2/3T_c = T\left(\frac{V_1}{V_2}\right)^{2/3}

Step 4: Evaluate the statements for V2/V1=8V_2/V_1 = 8.

Let r=V2V1=8r = \frac{V_2}{V_1} = 8.

Calculate the heat input Qin=QabQ_{\text{in}} = Q_{ab}:

Qab=nRTln⁡8=3nRTln⁡2Q_{ab} = nRT\ln 8 = 3nRT\ln 2

Using ln⁡2≈0.7\ln 2 \approx 0.7:

Qab≈2.10 nRTQ_{ab} \approx 2.10\,nRT

Calculate the temperature TcT_c:

Tc=T(18)2/3=T4T_c = T\left(\frac{1}{8}\right)^{2/3} = \frac{T}{4}

This gives:

Ta=4TcT_a = 4T_c

Thus, Statement (3) is correct.

Calculate the heat output Qout=QbcQ_{\text{out}} = Q_{bc}:

Qbc=32nR(T−T4)=98nRT≈1.125 nRTQ_{bc} = \frac{3}{2}nR\left(T - \frac{T}{4}\right) = \frac{9}{8}nRT \approx 1.125\,nRT

Comparing the heat values:

Qbc<QabQ_{bc} < Q_{ab}

Thus, Statement (1) is correct.

Step 5: Analyze the efficiency of the cycle.

The efficiency η\eta is given by:

η=1−QoutQin=1−QbcQab\eta = 1 - \frac{Q_{\text{out}}}{Q_{\text{in}}} = 1 - \frac{Q_{bc}}{Q_{ab}}

Substitute the expressions for QbcQ_{bc} and QabQ_{ab}:

η=1−32nRT(1−r−2/3)nRTln⁡r\eta = 1 - \frac{\frac{3}{2}nRT\left(1 - r^{-2/3}\right)}{nRT\ln r} η=1−32(1−r−2/3)ln⁡r\eta = 1 - \frac{\frac{3}{2}\left(1 - r^{-2/3}\right)}{\ln r}

Since η\eta depends only on the volume ratio rr and is independent of the temperature TT, Statement (2) is correct.

Step 6: Analyze the pressure ratio.

For the isothermal process a→ba \to b:

PaV1=PbV2P_a V_1 = P_b V_2 PaPb=V2V1=8\frac{P_a}{P_b} = \frac{V_2}{V_1} = 8

Thus, Statement (4) is incorrect.

Answer: The correct statements are (1), (2), and (3).

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