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JEE Advanced 2026 · Thermodynamics

Ten moles of an ideal monoatomic gas, initially in state aa at atmospheric pressure and temperature Ta=27∘CT_a=27^\circ\text{C}, is enclosed in a metal cylinder of volume V0V_0 fitted with a frictionless piston. The gas is suddenly compressed to state bb with volume V0/3V_0/3. Now, keeping the piston stationary, the cylinder is submerged in a water bath of temperature 11∘C11^\circ\text{C} until the gas reaches the temperature of the water bath, which is denoted as state cc. Finally, while still in the water bath, the piston is brought slowly to its initial position, which is denoted as state ff. If RR is universal gas constant, then the correct option(s) is/are: [Given: 91/3=2.089^{1/3}=2.08]

Diagram for this Thermodynamics question (JEE Advanced 2026).

Answers: A. The schematic PP-VV diagram of the processes described above is: · B. The change in internal energy in going from state aa to bb is 4860R4860R. · C. The net change in the internal energy in the whole process is −240R-240R.

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Written solution

Step 1: Identify the parameters of the gas and the states.

For a monoatomic ideal gas, the heat capacity at constant volume CVC_V and the adiabatic index γ\gamma are:

CV=32RC_V = \frac{3}{2}R γ=53\gamma = \frac{5}{3}

The initial state aa parameters are:

n=10 moln = 10\text{ mol} Ta=27∘C=300 KT_a = 27^\circ\text{C} = 300\text{ K} Va=V0V_a = V_0

Step 2: Analyze the adiabatic compression from state aa to state bb.

Since the gas is suddenly compressed, the process a→ba \to b is adiabatic. The volume at state bb is Vb=V03V_b = \frac{V_0}{3}.

Find the temperature TbT_b using the adiabatic relation:

Tb=Ta(VaVb)γ−1T_b = T_a \left(\frac{V_a}{V_b}\right)^{\gamma - 1} Tb=300×32/3T_b = 300 \times 3^{2/3}

Using the given value 91/3=32/3=2.089^{1/3} = 3^{2/3} = 2.08:

Tb=300×2.08=624 KT_b = 300 \times 2.08 = 624\text{ K}

Step 3: Calculate the change in internal energy for the process a→ba \to b.

ΔUa→b=nCV(Tb−Ta)\Delta U_{a\to b} = n C_V (T_b - T_a) ΔUa→b=10×32R×(624−300)\Delta U_{a\to b} = 10 \times \frac{3}{2}R \times (624 - 300) ΔUa→b=15R×324=4860R\Delta U_{a\to b} = 15R \times 324 = 4860R

Thus, option (2) is correct.

Step 4: Analyze the processes b→cb \to c and c→fc \to f.

In process b→cb \to c, the piston is stationary (isochoric process) and the gas cools to the water bath temperature:

Tc=11∘C=284 KT_c = 11^\circ\text{C} = 284\text{ K}

In process c→fc \to f, the gas undergoes isothermal expansion back to the initial volume:

Tf=Tc=284 KT_f = T_c = 284\text{ K} Vf=V0V_f = V_0

Step 5: Calculate the net change in internal energy for the entire process.

Since internal energy is a state function, the net change depends only on the initial and final temperatures:

ΔUnet=nCV(Tf−Ta)\Delta U_{\text{net}} = n C_V (T_f - T_a) ΔUnet=10×32R×(284−300)\Delta U_{\text{net}} = 10 \times \frac{3}{2}R \times (284 - 300) ΔUnet=15R×(−16)=−240R\Delta U_{\text{net}} = 15R \times (-16) = -240R

Thus, option (3) is correct.

Step 6: Calculate the pressure at state bb.

Using the adiabatic relation for pressure:

Pb=Pa(VaVb)γP_b = P_a \left(\frac{V_a}{V_b}\right)^{\gamma} Pb=1 atm×35/3P_b = 1\text{ atm} \times 3^{5/3} Pb=3×32/3=3×2.08=6.24 atmP_b = 3 \times 3^{2/3} = 3 \times 2.08 = 6.24\text{ atm}

Since Pb=6.24 atm≠2.08 atmP_b = 6.24\text{ atm} \neq 2.08\text{ atm}, option (4) is incorrect.

Step 7: Verify the P−VP-V diagram.

The processes are:

  • a→ba \to b: Adiabatic compression (curve rising to the left)
  • b→cb \to c: Isochoric cooling (vertical line downwards)
  • c→fc \to f: Isothermal expansion (curve going to the right)

This sequence matches the described P−VP-V diagram, so option (1) is correct.

Answer: The correct options are (1), (2), and (3).

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