Ten moles of an ideal monoatomic gas, initially in state at atmospheric pressure and temperature , is enclosed in a metal cylinder of volume fitted with a frictionless piston. The gas is suddenly compressed to state with volume . Now, keeping the piston stationary, the cylinder is submerged in a water bath of temperature until the gas reaches the temperature of the water bath, which is denoted as state . Finally, while still in the water bath, the piston is brought slowly to its initial position, which is denoted as state . If is universal gas constant, then the correct option(s) is/are: [Given: ]
Answers: A. The schematic - diagram of the processes described above is: · B. The change in internal energy in going from state to is . · C. The net change in the internal energy in the whole process is .
Or read the worked solution below. Jump to the steps ↓
Written solution
Step 1: Identify the parameters of the gas and the states.
For a monoatomic ideal gas, the heat capacity at constant volume and the adiabatic index are:
The initial state parameters are:
Step 2: Analyze the adiabatic compression from state to state .
Since the gas is suddenly compressed, the process is adiabatic. The volume at state is .
Find the temperature using the adiabatic relation:
Using the given value :
Step 3: Calculate the change in internal energy for the process .
Thus, option (2) is correct.
Step 4: Analyze the processes and .
In process , the piston is stationary (isochoric process) and the gas cools to the water bath temperature:
In process , the gas undergoes isothermal expansion back to the initial volume:
Step 5: Calculate the net change in internal energy for the entire process.
Since internal energy is a state function, the net change depends only on the initial and final temperatures:
Thus, option (3) is correct.
Step 6: Calculate the pressure at state .
Using the adiabatic relation for pressure:
Since , option (4) is incorrect.
Step 7: Verify the diagram.
The processes are:
- : Adiabatic compression (curve rising to the left)
- : Isochoric cooling (vertical line downwards)
- : Isothermal expansion (curve going to the right)
This sequence matches the described diagram, so option (1) is correct.
Answer: The correct options are (1), (2), and (3).