arthham

JEE Advanced 2009 · Thermodynamics

The figure shows the PP-VV plot of an ideal gas taken through a cycle ABCDAABCDA. The part ABCABC is a semi-circle and CDACDA is half of an ellipse. Then,

Answers: B. heat flows out of the gas during the path B→C→DB \rightarrow C \rightarrow D · D. positive work is done by the gas in the cycle ABCDAABCDA

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Written solution

Step 1: Analyze the path A→BA \to B.

For an isothermal process of an ideal gas, the product of pressure and volume must remain constant.

PV=constantPV = \text{constant}

At the endpoints A(2,3)A(2,3) and B(3,2)B(3,2), the product is equal.

PAVA=PBVB=6P_A V_A = P_B V_B = 6

However, along the semi-circular path connecting AA and BB, the product PVPV varies and reaches a maximum value of approximately 7.337.33.

PV≠constantPV \neq \text{constant}

Therefore, the path A→BA \to B is not isothermal.

Step 2: Analyze the path B→C→DB \to C \to D.

Determine the sign of the heat exchange using the First Law of Thermodynamics.

Q=ΔU+WQ = \Delta U + W

Along this path, both temperature and volume decrease, meaning both the change in internal energy and work done are negative.

ΔU<0\Delta U < 0 W<0W < 0

Since both terms are negative, the net heat exchange is negative, meaning heat flows out of the gas.

Q<0Q < 0

Step 3: Calculate the work done along the path A→B→CA \to B \to C.

The work done is represented by the area under the path on the PP-VV diagram.

WA→B→C=∫P dVW_{A \to B \to C} = \int P \, dV

This integral corresponds to the area of the right semi-circle.

WA→B→C=π2≠0W_{A \to B \to C} = \frac{\pi}{2} \neq 0

Step 4: Determine the net work done in the cycle ABCDAABCDA.

The cycle is traversed in a clockwise direction.

Wcycle=∮P dVW_{\text{cycle}} = \oint P \, dV

For a clockwise cycle, the net work done by the gas is positive and equal to the enclosed area of the semi-circle and semi-ellipse.

Wcycle=π2+πa2>0W_{\text{cycle}} = \frac{\pi}{2} + \frac{\pi a}{2} > 0

Answer: The correct statements are:

  • Heat flows out of the gas during path B→C→DB \to C \to D.
  • Positive work is done by the gas in the cycle ABCDAABCDA.

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