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JEE Advanced 2010 · Thermal Properties of Matter

A piece of ice (heat capacity =2100 J kg−1 ∘C−1= 2100\,\text{J kg}^{-1}\,^\circ\text{C}^{-1} and latent heat =3.36×105 J kg−1= 3.36 \times 10^{5}\,\text{J kg}^{-1}) of mass mm grams is at −5∘C-5^\circ\text{C} at atmospheric pressure. It is given 420 J420\,\text{J} of heat so that the ice starts melting. Finally when the ice-water mixture is in equilibrium, it is found that 1 gm1\,\text{gm} of ice has melted. Assuming there is no other heat exchange in the process, the value of mm is

Answer: 99

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Written solution

Step 1: Identify the given parameters.

Convert the mass of ice and the mass of melted ice into kilograms.

Mass of ice=m g=m1000 kg\text{Mass of ice} = m \text{ g} = \frac{m}{1000} \text{ kg} Mass of melted ice=1 g=10−3 kg\text{Mass of melted ice} = 1 \text{ g} = 10^{-3} \text{ kg} Specific heat capacity of ice, c=2100 J kg−1 ∘C−1\text{Specific heat capacity of ice, } c = 2100 \text{ J kg}^{-1} \text{ }^\circ\text{C}^{-1} Latent heat of fusion, L=3.36×105 J kg−1\text{Latent heat of fusion, } L = 3.36 \times 10^{5} \text{ J kg}^{-1} Total heat supplied, Q=420 J\text{Total heat supplied, } Q = 420 \text{ J}

Step 2: Calculate the heat required to raise the temperature of the ice.

The heat Q1Q_1 required to raise the temperature of mm grams of ice from −5∘C-5^\circ\text{C} to 0∘C0^\circ\text{C} is given by:

Q1=(m1000)⋅c⋅ΔTQ_1 = \left(\frac{m}{1000}\right) \cdot c \cdot \Delta T Q1=(m1000)⋅(2100)⋅(0−(−5))Q_1 = \left(\frac{m}{1000}\right) \cdot (2100) \cdot (0 - (-5)) Q1=10.5m JQ_1 = 10.5m \text{ J}

Step 3: Calculate the heat required to melt the ice.

The heat Q2Q_2 required to melt 1 g1\text{ g} of ice at 0∘C0^\circ\text{C} is given by:

Q2=(10−3 kg)⋅LQ_2 = (10^{-3} \text{ kg}) \cdot L Q2=10−3⋅(3.36×105)Q_2 = 10^{-3} \cdot (3.36 \times 10^{5}) Q2=336 JQ_2 = 336 \text{ J}

Step 4: Apply the principle of conservation of energy.

The total heat supplied is the sum of the heat used to raise the temperature and the heat used for melting.

Q1+Q2=QQ_1 + Q_2 = Q 10.5m+336=42010.5m + 336 = 420 10.5m=8410.5m = 84 m=8410.5m = \frac{84}{10.5} m=8m = 8

Answer: The value of mm is 8.

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