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JEE Advanced 2012 · Thermal Properties of Matter

Assume that a drop of liquid evaporates by decrease in its surface energy, so that its temperature remains unchanged. What should be the minimum radius of the drop for this to be possible? The surface tension is TT, density of liquid is ρ\rho and LL is its latent heat of vaporization.

Answer: D. 2T/ρL2T/\rho L

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Written solution

Step 1: Express the surface energy of the drop.

The surface energy EsE_s of a spherical drop of radius rr with surface tension TT is given by the product of surface tension and surface area.

Es=4πr2TE_s = 4\pi r^2 T

Step 2: Relate the change in surface energy to a change in radius.

Let the radius of the drop decrease by drdr during evaporation.

dEs=8πrT drdE_s = 8\pi r T \, dr

Step 3: Relate the mass of the evaporated liquid to the change in radius.

The mass dmdm of the evaporated liquid is the product of density ρ\rho and the change in volume dVdV.

dm=4πr2ρ drdm = 4\pi r^2 \rho \, dr

Step 4: Set up the energy conservation condition.

The released surface energy must be at least equal to the latent heat needed for vaporization.

dEs≥L dmdE_s \ge L \, dm

Step 5: Solve for the radius rr.

Substitute the expressions for dEsdE_s and dmdm into the inequality.

8πrT dr≥4πr2ρL dr8\pi r T \, dr \ge 4\pi r^2 \rho L \, dr

Simplify the inequality to find the condition for rr.

2T≥rρL2T \ge r \rho L r≤2TρLr \le \frac{2T}{\rho L}

The critical radius for this process is the limiting value.

r=2TρLr = \frac{2T}{\rho L}

Answer: The minimum radius of the drop is 2TρL\dfrac{2T}{\rho L}.

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