arthham

JEE Advanced 2014 · Thermodynamics

A thermodynamic system is taken from an initial state i with internal energy Ui=100JU_{i} = 100 J to the final state f along two different paths iaf and ibf, as schematically shown in the figure. The work done by the system along the paths af, ib and bf are Waf=200J,Wib=50JW_{af} = 200 J, W_{ib} = 50 J and Wbf=100JW_{bf} = 100 J respectively. The heat supplied to the system along the path iaf, ib and bf are Qiaf,QibQ_{iaf}, Q_{ib} and QbfQ_{bf} respectively. If the internal energy of the system in the state b is Ub=200JU_{b} = 200 J and Qiaf=500J,Q_{iaf} = 500 J, the ratio Qbf/QibQ_{bf} / Q_{ib} is

Answer: 22

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Step 1: Identify the given parameters.

The given values for internal energy, work, and heat are listed below.

Ui=100 JU_i = 100\text{ J} Waf=200 JW_{af} = 200\text{ J} Wib=50 JW_{ib} = 50\text{ J} Wbf=100 JW_{bf} = 100\text{ J} Ub=200 JU_b = 200\text{ J} Qiaf=500 JQ_{iaf} = 500\text{ J}

Step 2: Determine the work done along path iaia.

Since the path i→ai \to a is vertical on the P-VP\text{-}V diagram, the volume remains constant.

ΔV=0\Delta V = 0 Wia=0 JW_{ia} = 0\text{ J}

Step 3: Calculate the total work done along path iafiaf.

Sum the work done along the segments iaia and afaf.

Wiaf=Wia+WafW_{iaf} = W_{ia} + W_{af} Wiaf=0+200=200 JW_{iaf} = 0 + 200 = 200\text{ J}

Step 4: Calculate the internal energy of the final state ff.

Apply the first law of thermodynamics to the path iafiaf to find the change in internal energy.

Qiaf=ΔUiaf+WiafQ_{iaf} = \Delta U_{iaf} + W_{iaf} ΔUiaf=500−200=300 J\Delta U_{iaf} = 500 - 200 = 300\text{ J} Uf=Ui+ΔUiafU_f = U_i + \Delta U_{iaf} Uf=100+300=400 JU_f = 100 + 300 = 400\text{ J}

Step 5: Calculate the heat supplied along path ibib.

Apply the first law of thermodynamics to the path ibib.

ΔUib=Ub−Ui\Delta U_{ib} = U_b - U_i ΔUib=200−100=100 J\Delta U_{ib} = 200 - 100 = 100\text{ J} Qib=ΔUib+WibQ_{ib} = \Delta U_{ib} + W_{ib} Qib=100+50=150 JQ_{ib} = 100 + 50 = 150\text{ J}

Step 6: Calculate the heat supplied along path bfbf.

Apply the first law of thermodynamics to the path bfbf.

ΔUbf=Uf−Ub\Delta U_{bf} = U_f - U_b ΔUbf=400−200=200 J\Delta U_{bf} = 400 - 200 = 200\text{ J} Qbf=ΔUbf+WbfQ_{bf} = \Delta U_{bf} + W_{bf} Qbf=200+100=300 JQ_{bf} = 200 + 100 = 300\text{ J}

Step 7: Calculate the ratio of the heats.

Divide the heat supplied along path bfbf by the heat supplied along path ibib.

QbfQib=300150\frac{Q_{bf}}{Q_{ib}} = \frac{300}{150} QbfQib=2\frac{Q_{bf}}{Q_{ib}} = 2

Answer: The ratio QbfQib\dfrac{Q_{bf}}{Q_{ib}} is 22.

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