arthham

JEE Advanced 2019 · Thermodynamics

A mixture of ideal gas containing 5 moles of monatomic gas and 1 mole of rigid diatomic gas is initially at pressure P0P_0, volume V0V_0, and temperature T0T_0. If the gas mixture is adiabatically compressed to a volume V0/4V_0/4, then the correct statement(s) is/are. (Given 21.2=2.32^{1.2}=2.3; 23.2=9.22^{3.2}=9.2; RR is gas constant)

Answers: A. The work ∣W∣|W| done during the process is 13RT013RT_0 · B. The final pressure of the gas mixture after compression is in between 9P09P_0 and 10P010P_0 · D. Adiabatic constant of the gas mixture is 1.6

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Written solution

Step 1: Calculate the molar heat capacity and adiabatic exponent of the mixture.

The molar heat capacities at constant volume for monatomic and rigid diatomic gases are:

CV,1=32RC_{V,1} = \frac{3}{2}R CV,2=52RC_{V,2} = \frac{5}{2}R

The molar heat capacity of the mixture is:

CV,mix=n1CV,1+n2CV,2n1+n2C_{V,\text{mix}} = \frac{n_1 C_{V,1} + n_2 C_{V,2}}{n_1 + n_2}

Substitute n1=5n_1 = 5 and n2=1n_2 = 1:

CV,mix=5(32R)+1(52R)5+1C_{V,\text{mix}} = \frac{5\left(\frac{3}{2}R\right) + 1\left(\frac{5}{2}R\right)}{5 + 1} CV,mix=53RC_{V,\text{mix}} = \frac{5}{3}R

The adiabatic exponent of the mixture is:

γ=1+RCV,mix\gamma = 1 + \frac{R}{C_{V,\text{mix}}} γ=1+35\gamma = 1 + \frac{3}{5} γ=1.6\gamma = 1.6

Step 2: Determine the final temperature and pressure.

For an adiabatic process, the temperature-volume and pressure-volume relations are:

Tf=T0(V0Vf)γ−1T_f = T_0 \left(\frac{V_0}{V_f}\right)^{\gamma-1} Pf=P0(V0Vf)γP_f = P_0 \left(\frac{V_0}{V_f}\right)^{\gamma}

Substitute Vf=V04V_f = \frac{V_0}{4} and γ=1.6\gamma = 1.6:

Tf=T0(4)0.6T_f = T_0 (4)^{0.6} Tf=T0(2)1.2T_f = T_0 (2)^{1.2} Tf=2.3T0T_f = 2.3 T_0

Now calculate the final pressure:

Pf=P0(4)1.6P_f = P_0 (4)^{1.6} Pf=P0(2)3.2P_f = P_0 (2)^{3.2} Pf=9.2P0P_f = 9.2 P_0

Since 9P0<Pf<10P09 P_0 < P_f < 10 P_0, the statement about the final pressure is correct.

Step 3: Calculate the work done on the gas.

For an adiabatic process, the work done on the gas equals the change in internal energy:

Won=ΔUW_{\text{on}} = \Delta U Won=nCV,mix(Tf−T0)W_{\text{on}} = n C_{V,\text{mix}} (T_f - T_0)

Substitute n=6n = 6, CV,mix=53RC_{V,\text{mix}} = \frac{5}{3}R, and the temperatures:

Won=6(53R)(2.3T0−T0)W_{\text{on}} = 6 \left(\frac{5}{3}R\right) (2.3 T_0 - T_0) Won=10R(1.3T0)W_{\text{on}} = 10 R (1.3 T_0) Won=13RT0W_{\text{on}} = 13 R T_0

Step 4: Calculate the final internal energy.

The final internal energy of the mixture is:

Uf=nCV,mixTfU_f = n C_{V,\text{mix}} T_f Uf=6(53R)(2.3T0)U_f = 6 \left(\frac{5}{3}R\right) (2.3 T_0) Uf=23RT0U_f = 23 R T_0

Since 23RT023 R T_0 is not in the range (18RT0,19RT0)(18 R T_0, 19 R T_0), the statement regarding the final internal energy is incorrect.

Answer: The correct statements are:

  • The work done on the gas is 13RT013 R T_0.
  • The final pressure PfP_f of the gas is between 9P09 P_0 and 10P010 P_0.
  • The adiabatic constant γ\gamma of the mixture is 1.61.6.

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