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JEE Advanced 2019 · Thermodynamics

One mole of a monatomic ideal gas goes through a thermodynamic cycle, as shown in the volume versus temperature (V−T)(V-T) diagram. The correct statement(s) is/are: [RR is the gas constant]

Answers: A. Work done in this thermodynamic cycle (1→2→3→4→1)(1 \to 2 \to 3 \to 4 \to 1) is ∣W∣=12RT0|W| = \frac{1}{2}RT_0 · C. The ratio of heat transfer during processes 1→21 \to 2 and 3→43 \to 4 is ∣Q1→2∣∣Q2→3∣=53\frac{|Q_{1 \to 2}|}{|Q_{2 \to 3}|} = \frac{5}{3}

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Written solution

Step 1: Identify the properties of the gas.

For 11 mole of a monatomic ideal gas, the molar heat capacities at constant volume (CVC_V) and constant pressure (CPC_P) are:

CV=32RC_V = \frac{3}{2}R CP=52RC_P = \frac{5}{2}R

Step 2: Analyze each process in the cycle.

Identify the nature of each transition in the V−TV-T diagram:

  • For 1→21 \to 2 and 3→43 \to 4, the path is a straight line passing through the origin, meaning V∝TV \propto T. By the ideal gas law (PV=nRTPV = nRT), constant VT\frac{V}{T} implies constant pressure. Thus, these processes are isobaric.
  • For 2→32 \to 3 and 4→14 \to 1, the volume remains constant. Thus, these processes are isochoric.

Since there are no adiabatic processes in the cycle, statement (2) is false.

Step 3: Calculate the work done in each process.

Work done in the isochoric processes is zero:

W23=W41=0W_{23} = W_{41} = 0

Work done in the isobaric processes is given by W=nRΔTW = nR\Delta T:

W12=R(2T0−T0)=RT0W_{12} = R(2T_0 - T_0) = RT_0 W34=R(T02−T0)=−12RT0W_{34} = R\left(\frac{T_0}{2} - T_0\right) = -\frac{1}{2}RT_0

The net work done in the cycle is:

Wnet=W12+W23+W34+W41W_{\text{net}} = W_{12} + W_{23} + W_{34} + W_{41} Wnet=RT0+0−12RT0+0=12RT0W_{\text{net}} = RT_0 + 0 - \frac{1}{2}RT_0 + 0 = \frac{1}{2}RT_0

Thus, statement (1) is true.

Step 4: Calculate the heat transfer in each process.

For the isobaric processes, the heat transfer is Q=nCPΔTQ = nC_P\Delta T:

Q1→2=52R(2T0−T0)=52RT0Q_{1\to2} = \frac{5}{2}R(2T_0 - T_0) = \frac{5}{2}RT_0 Q3→4=52R(T02−T0)=−54RT0Q_{3\to4} = \frac{5}{2}R\left(\frac{T_0}{2} - T_0\right) = -\frac{5}{4}RT_0

For the isochoric processes, the heat transfer is Q=nCVΔTQ = nC_V\Delta T:

Q2→3=32R(T0−2T0)=−32RT0Q_{2\to3} = \frac{3}{2}R(T_0 - 2T_0) = -\frac{3}{2}RT_0 Q4→1=32R(T0−T02)=34RT0Q_{4\to1} = \frac{3}{2}R\left(T_0 - \frac{T_0}{2}\right) = \frac{3}{4}RT_0

Step 5: Evaluate the ratios of heat transfers.

Calculate the ratio for statement (3):

∣Q1→2∣∣Q2→3∣=52RT032RT0=53\frac{|Q_{1\to2}|}{|Q_{2\to3}|} = \frac{\frac{5}{2}RT_0}{\frac{3}{2}RT_0} = \frac{5}{3}

Thus, statement (3) is true.

Calculate the ratio for statement (4):

∣Q1→2∣∣Q3→4∣=52RT054RT0=2\frac{|Q_{1\to2}|}{|Q_{3\to4}|} = \frac{\frac{5}{2}RT_0}{\frac{5}{4}RT_0} = 2

Thus, statement (4) is false.

Answer: The correct statements are (1) and (3).

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