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JEE Advanced 2020 · Thermodynamics

Consider one mole of helium gas enclosed in a container at initial pressure P1P_1 and volume V1V_1. It expands isothermally to volume 4V14V_1. After this, the gas expands adiabatically and its volume becomes 32V132V_1. The work done by the gas during isothermal and adiabatic expansion processes are WisoW_{iso} and WadiaW_{adia} respectively. If the ratio WisoWadia=fln⁡2\frac{W_{iso}}{W_{adia}} = f \ln 2, then ff is ______.

Answer: 1.77to1.781.77 to 1.78

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Written solution

Step 1: Identify the properties of Helium gas.

Helium is a monatomic gas, which determines its heat capacities and adiabatic index γ\gamma.

CV=32RC_V = \frac{3}{2}R CP=52RC_P = \frac{5}{2}R γ=CPCV=53\gamma = \frac{C_P}{C_V} = \frac{5}{3}

Step 2: Calculate the work done during the isothermal expansion.

The gas expands isothermally at temperature T1T_1 from volume V1V_1 to 4V14V_1.

Wiso=nRT1ln⁡(4V1V1)W_{\text{iso}} = nRT_1 \ln\left(\frac{4V_1}{V_1}\right) Wiso=P1V1ln⁡4W_{\text{iso}} = P_1V_1 \ln 4 Wiso=2P1V1ln⁡2W_{\text{iso}} = 2P_1V_1 \ln 2

Step 3: Determine the final temperature after the adiabatic expansion.

The gas expands adiabatically from volume 4V14V_1 to 32V132V_1.

T1(4V1)γ−1=T2(32V1)γ−1T_1 (4V_1)^{\gamma-1} = T_2 (32V_1)^{\gamma-1} T2=T1(4V132V1)γ−1T_2 = T_1 \left(\frac{4V_1}{32V_1}\right)^{\gamma-1} T2=T1(18)2/3T_2 = T_1 \left(\frac{1}{8}\right)^{2/3} T2=T14T_2 = \frac{T_1}{4}

Step 4: Calculate the work done during the adiabatic expansion.

Use the formula for work done in an adiabatic process.

Wadia=nR(T1−T2)γ−1W_{\text{adia}} = \frac{nR(T_1 - T_2)}{\gamma - 1} Wadia=nR(T1−T14)53−1W_{\text{adia}} = \frac{nR\left(T_1 - \frac{T_1}{4}\right)}{\frac{5}{3} - 1} Wadia=34nRT123W_{\text{adia}} = \frac{\frac{3}{4}nRT_1}{\frac{2}{3}} Wadia=98P1V1W_{\text{adia}} = \frac{9}{8}P_1V_1

Step 5: Find the ratio of the work done to determine ff.

Divide the isothermal work by the adiabatic work.

WisoWadia=2P1V1ln⁡298P1V1\frac{W_{\text{iso}}}{W_{\text{adia}}} = \frac{2P_1V_1 \ln 2}{\frac{9}{8}P_1V_1} WisoWadia=169ln⁡2\frac{W_{\text{iso}}}{W_{\text{adia}}} = \frac{16}{9} \ln 2

Comparing this to the given relation WisoWadia=fln⁡2\frac{W_{\text{iso}}}{W_{\text{adia}}} = f \ln 2 yields the value of ff.

f=169f = \frac{16}{9}

Answer: 169\dfrac{16}{9}

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