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JEE Advanced 2022 · Thermodynamics

In the given PP-VV diagram, a monatomic gas (γ=53)\left(\gamma = \frac{5}{3}\right) is first compressed adiabatically from state AA to state BB. Then it expands isothermally from state BB to state CC. [Given (13)0.6=0.5\left(\frac{1}{3}\right)^{0.6} = 0.5, ln⁡2=0.7\ln 2 = 0.7]. Which of the following statement(s) is(are) correct?

Answers: B. The magnitude of the work done in the process B→CB \to C is 84 kJ84\,\text{kJ}. · C. The magnitude of the work done in the process A→BA \to B is 60 kJ60\,\text{kJ}. · D. The magnitude of the work done in the process C→AC \to A is zero.

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Written solution

Step 1: Identify the state variables for each state.

From the given PP-VV diagram, we identify the coordinates of the states.

VA=0.80 m3,PA=100 kPaV_A = 0.80\,\text{m}^3,\quad P_A = 100\,\text{kPa} PB=300 kPaP_B = 300\,\text{kPa} VC=0.80 m3V_C = 0.80\,\text{m}^3

Step 2: Find the volume at state BB.

Since the process A→BA \to B is adiabatic, we use the adiabatic relation.

PAVAγ=PBVBγP_A V_A^{\gamma} = P_B V_B^{\gamma} VB=VA(PAPB)1/γV_B = V_A \left(\frac{P_A}{P_B}\right)^{1/\gamma}

Substitute γ=53\gamma = \frac{5}{3} and the given values.

VB=0.80×(100300)0.6V_B = 0.80 \times \left(\frac{100}{300}\right)^{0.6} VB=0.80×(13)0.6V_B = 0.80 \times \left(\frac{1}{3}\right)^{0.6}

Using the approximation (13)0.6=0.5\left(\frac{1}{3}\right)^{0.6} = 0.5:

VB=0.80×0.5=0.40 m3V_B = 0.80 \times 0.5 = 0.40\,\text{m}^3

Step 3: Find the pressure at state CC.

Since the process B→CB \to C is isothermal, the temperature remains constant.

PBVB=PCVCP_B V_B = P_C V_C PC=PBVBVCP_C = \frac{P_B V_B}{V_C} PC=300×0.400.80=150 kPaP_C = \frac{300 \times 0.40}{0.80} = 150\,\text{kPa}

Step 4: Calculate the work done during the adiabatic compression A→BA \to B.

Use the formula for work done in an adiabatic process.

WAB=PAVA−PBVBγ−1W_{AB} = \frac{P_A V_A - P_B V_B}{\gamma - 1} WAB=(100×0.80)−(300×0.40)53−1W_{AB} = \frac{(100 \times 0.80) - (300 \times 0.40)}{\frac{5}{3} - 1} WAB=80−1202/3=−60 kJW_{AB} = \frac{80 - 120}{2/3} = -60\,\text{kJ}

The magnitude of this work is:

∣WAB∣=60 kJ|W_{AB}| = 60\,\text{kJ}

Step 5: Calculate the work done during the isothermal expansion B→CB \to C.

Use the formula for work done in an isothermal process.

WBC=PBVBln⁡(VCVB)W_{BC} = P_B V_B \ln\left(\frac{V_C}{V_B}\right) WBC=(300×0.40)ln⁡(0.800.40)W_{BC} = (300 \times 0.40) \ln\left(\frac{0.80}{0.40}\right) WBC=120ln⁡2W_{BC} = 120 \ln 2

Using the approximation ln⁡2=0.7\ln 2 = 0.7:

WBC=120×0.7=84 kJW_{BC} = 120 \times 0.7 = 84\,\text{kJ}

Step 6: Calculate the work done during the process C→AC \to A.

Since VC=VA=0.80 m3V_C = V_A = 0.80\,\text{m}^3, this is an isochoric process.

WCA=0 kJW_{CA} = 0\,\text{kJ}

Step 7: Calculate the total work done in the cycle.

Sum the work done in each individual step.

Wtotal=WAB+WBC+WCAW_{\text{total}} = W_{AB} + W_{BC} + W_{CA} Wtotal=−60+84+0=24 kJW_{\text{total}} = -60 + 84 + 0 = 24\,\text{kJ}

Answer: The correct statements are:

  • Magnitude of work done during B→CB \to C is 84 kJ84\,\text{kJ}
  • Magnitude of work done during A→BA \to B is 60 kJ60\,\text{kJ}
  • Work done during C→AC \to A is 00

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